EnvironmentalCorner
Performance Plastics Provide Sustainable Clean Water Solution for the World
By Duvon McGuire, New Life International; Mary Hyde, ALTAFLO, A Pexco Company; Alexandra Peters, Arkema; and Marco DeAngelo, Arkema
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ew Life International, a non-profit organization based in Underwood, IN, USA, has provided safe water to communities around the world with a cost-effective and simple-to-operate water purification system since 1998.

New Life’s President Duvon McGuire learned the risks of unsafe water as a child. While serving in Ecuador with his missionary family, he contracted a nearly fatal infection from contaminated water. Motivated to study pre-med and chemistry in college, McGuire eventually traveled to India, working in hospitals and witnessing firsthand the health perils and needless deaths resulting from unsafe water.

Through years of research and experimentation, McGuire invented an affordable, lightweight and portable water purifier that can disinfect large amounts of water quickly for entire communities. Since 1998, thousands of recipients in more than 80 countries have received these purifiers, providing safe water to individuals, schools, hospitals and entire communities. The ongoing development and distribution of the water purifiers is managed through New Life International.

New Life International’s H2autO water purifier unit
New Life International’s H2autO water purifier unit in Underwood, IN, USA using Kynar® PVDF tube fittings and Kynar PVDF tubing.
Sustainability concerns
While the critical need for pure water remains unchanged, environmental concerns have grown in recent years. Initiatives to improve the quality of life for populations residing in areas with little access to vital resources must focus on both the long- and short-term impact of the materials used to create solutions. Unfortunately, as McGuire has observed, this approach is not consistently employed:

“When people talk about meeting the unmet needs of the poor, they often mention sustainable technology and appropriate technology. They talk about these things as if they were looking for “once and done” – but careful observation tells an entirely different story. Sustainability and appropriate technology end up in a circular firing squad of least initial cost and frequent repairs — with little thought given to true long-term costs.”

McGuire’s concerns led him and his team to explore advanced material solutions for the components used in their water purifiers. His search for more sustainable alternatives led him to polyvinylidene fluoride (PVDF), a high-performance fluoropolymer, and material supplier Arkema’s Kynar® Flex PVDF Copolymer and tubing supplier Altaflo as new partners in the investigation process. Their combined efforts are addressing ways to use high-performance polymers and advanced tubing solutions to create a better quality of life through the delivery of safer water and wastewater management.

According to USA Today, “More people die each year from unsafe water than from all forms of violence, including war.”
Why Kynar for chlorination systems?
New Life International’s water purifier creates chlorine from table salt to disinfect water and make it safe for drinking. It features a simple, unique design, constructed for use in harsh environmental conditions with limited resource availability. The water purifier uses table salt and water to create chlorine which kills harmful bacteria in the water. The purifier can treat up to 55 gallons per minute depending upon water quality and the size of the unit.

Since the water purifier systems were designed for use in countries all over the world, with varying climates and environments, many material properties were considered when designing the system to meet critical set up requirements, including:

  • Resistance to chlorine: Chlorine, a strong oxidizing agent, is a main component of the New Life International Water Purifier as it kills the disease-causing bacteria and viruses to create clean, drinkable water.
  • Purity: A pure material without additives will eliminate concerns of potential leaching and adding additional contaminants into the water.
  • Service life: Systems could be placed in remote locations where it may present challenges to get replacement parts in a timely manner.
  • Weatherability: The water purifiers may be located outdoors, exposing the materials to extremely hot or cold temperatures, humidity, strong winds and severe weather events.
  • Kink resistance: Kinking of the tubing can create problems with the flow of the system.
  • Regulatory certifications: Certifications for potable water contact, such as NSF 51 and NSF 61.
New Life International’s water purification system in Haiti
New Life International’s water purification system in Haiti.
New Life International found that Kynar Flex® PVDF Copolymer exhibited the characteristics they were looking for in the tubing design of the purifier system. It is a pure fluoropolymer known for its chemical, corrosion, UV and weathering resistance, with a history of use in a wide range of demanding industries, including general chemical, water treatment, biopharma, semiconductor, petrochemical, pulp and paper and nuclear processing. As a versatile material, it can be found for piping, storing and pumping corrosive acids and chlorinated chemistries offering engineers a material solution to cover a wide range of needs.

Kynar Flex PVDF Copolymer also has excellent weatherability characteristics. One of its oldest applications is for architectural coatings where it is used as a finish to protect building exteriors, helping to provide long-lasting protection and color retention. Along with the decades of outdoor applications, accelerated weathering tests have been completed on Kynar Flex PVDF Copolymer grades. These tests show no loss in tensile yield strength, elongation, optical or surface properties after 5,000 hours of QUVA exposure.

In addition to essential mechanical properties, it is important that materials in contact with drinking water comply with the regulatory requirements needed for the water purifier system. Kynar Flex PVDF Copolymer is NSF 51 and 61 certified, allowing its components to be safely used in the manufacture of drinking water as well as food. Unfilled Kynar Flex PVDF Copolymers meet the requirements for repeated contact with food per Title 21, Code of Federal Regulations, part 177.2600. Additionally, Kynar PVDF and Kynar Flex PVDF Copolymers are Kosher Certified by the Chicago Rabbinical Council (cRc) for year-round use and certain grades of Kynar Flex PVDF are Halal certified for food contact applications.

Altaflo Kynar Flex® PVDF tubing on a reel
Altaflo Kynar Flex® PVDF tubing straight lengths
Altaflo Kynar Flex® PVDF tubing was provided on reels or straight lengths as requested for this project. For combined exposure to sunlight and chlorine, it can be pigmented.
Tubing components
Once Kynar Flex PVDF Copolymer was selected as the material of choice, ALTAFLO, a Pexco Company, was introduced to New Life International due to their experience with the development of fluoropolymer tubing products for the water treatment industry. ALTAFLO was also well positioned to help provide critical testing that would assist with New Life’s humanitarian work around the globe. Both ALTAFLO and Arkema were open to ground floor participation of new concepts that would provide potable water in more sustainable ways.

New Life International’s water purifiers require tubing that can stand up to an extensive, non-negotiable set of rigorous demands in the field. Required capabilities include durability, inherent purity and extreme temperature and environmental resistance, often in wide ranging and potentially harsh climates. Specific tubing components exposed to sunlight may also require special treatments, such as an additional UV blocking pigment or simple covering to mitigate premature degradation risks that can accompany contact with chlorine-based solutions. ALTAFLO’s complete array of Kynar PVDF Homopolymer and Kynar Flex PVDF Copolymer tubing offered a solution for New Life International’s needs.

The water purifiers are available with two different tank styles: a one tank system and a two-tank gravity fed system, which requires additional tubing for routing water between tanks and offers greater processing capacity. Appropriate material selection is integral for each element of the application for both systems to maximize sustainability and ensure long, uninterrupted product life in the field. Beyond tubing, the tank systems include filtration components, filter housings, pumps and instrumentation. Kynar Flex PVDF provides a wide array of product lines ranging from super rigid to highly flexible. Application specific customization is available for varying grades to assure the right mix of properties of an application.

For New Life International’s unique application, ALTAFLO’s ability to create customized tubing to meet purifier unit specifications was vital. Evaluation of Arkema’s array of PVDF resin offerings involved the sampling, testing and retesting of material with varied wall thicknesses for the tubing. Initial testing of the Kynar Flex PVDF Copolymer tubing featured dimensions of 1/2″ inner diameter, 5/8″ outer diameter and a 1/16″ wall. ALTAFLO’s adaptability allowed for further testing on other tubing sizes to identify the best fit, including a 1/8″ wall, making it more resistant to kinking. The goal was to find the sweet spot between kink resistance and flexibility. ALTAFLO’s expertise has enabled them to create customized options based on their client’s specifications.

New Life International’s water purification system in Nepal
New Life International’s water purification system in Nepal.
Long lasting lifetime
New Life International is able to deliver pure water and improved quality of life to communities all over the world with their unique water purifier systems. Kynar Flex PVDF Copolymer tubing, a critical new component of these systems, will allow for longer service life in the varying climates and environments, due to the material’s purity, ductility, chemical resistance, weatherability and kink resistance. ALTAFLO and Arkema are continuing to work with New Life International to further this initiative and provide the best materials and components for high-quality potable water.

Duvon McGuire and the New Life International team are encouraged by the sustainability advancements already underway through their collaboration with Arkema and ALTAFLO — for both the water purifier recipients and the environments in which they’re being used.

“Designed obsolescence is not a useful concept in a sustainable circular economy. We have more than one choice. We can recycle while making things that don’t grow old, but we must get beyond the ‘recycle or throw away’ mentality. The value must be recovered long before the products arrive at the dumpster,” said Duvon McGuire. “If we lived in the middle of nowhere, what might we want for our families? The people may have near nothing, so something is better than nothing. However, if we were in their shoes, wouldn’t it be nice to have affordable solutions that did not repeatedly break down — or prematurely wind up in landfills? This is part of our challenge — creating lifesaving and life enhancing solutions that bring sustainable well-being to life.”

KYNAR® PVDF
TEST METHOD
KYNAR® 740
KYNAR FLEX® 2750
KYNAR SUPERFLEX® 2500
KYNAR® PVDF
Melting Point (°C / °F)
TEST METHOD
ASTM D3418
KYNAR® 740
168
KYNAR FLEX® 2750
135
KYNAR SUPERFLEX® 2500
123
KYNAR® PVDF
Specific Gravity
TEST METHOD
ASTM D792
KYNAR® 740
1.77
KYNAR FLEX® 2750
1.78
KYNAR SUPERFLEX® 2500
1.79
KYNAR® PVDF
Tensile Stength at Yield (psi)
TEST METHOD
ASTM D638
KYNAR® 740
7500
KYNAR FLEX® 2750
3000
KYNAR SUPERFLEX® 2500
2500
KYNAR® PVDF
Elongation at Break (%)
TEST METHOD
ASTM D638
KYNAR® 740
>20
KYNAR FLEX® 2750
>200
KYNAR SUPERFLEX® 2500
>400
KYNAR® PVDF
Hardness (shore D)
TEST METHOD
ASTM D2240
KYNAR® 740
78
KYNAR FLEX® 2750
57
KYNAR SUPERFLEX® 2500
52
KYNAR® PVDF
Flexural Modulus (x10-3 psi)
TEST METHOD
ASTM D790
KYNAR® 740
280
KYNAR FLEX® 2750
55
KYNAR SUPERFLEX® 2500
35
KYNAR® PVDF
Notched Impact Strength (ft-lbf/in)
TEST METHOD
ASTM D256
KYNAR® 740
3
KYNAR FLEX® 2750
NO BREAK
KYNAR SUPERFLEX® 2500
NO BREAK
KYNAR® PVDF
UL® Flame Class
TEST METHOD
UL 94
KYNAR® 740
V-0
KYNAR FLEX® 2750
V-0
KYNAR SUPERFLEX® 2500
V-0
Table 1: Kynar 740, Kynar Flex 2750, and Kynar Superflex® 2500 were all considered for the project with Kynar Superflex 2500 as the ultimate choice for flexibility and kink resistance.
Citations
  1. A. Palovcak; J. Pomante; “Prevent Corrosion With PVDF” Processing, July 2018 pp. 10-13
  2. A. Palovcak; J. Pomante; “A Fluoropolymer for Chemical Challenges” Chemical Engineering, August 2019 pp. 46-49
  3. A. Palovcak; B.Douglas; “Kynar® Fluoropolymer – A Solution for the Most Extreme Weathering Conditions” Plastictrends March 2017
Duvon McGuire holds a Bachelor of Science degree in chemistry/bio-pre-med from Asbury University. His expertise in producing safe water in the developing world spans more than 25 years. Since 2004, he has been President of New Life International, the 501(c)3 non-profit founded by his parents, Byron and Yvonne McGuire. duvon@waterfortheworld.com.

Mary Hyde’s expertise in fluoropolymer applications spans more than 35 years. She has spent her career creating a strong focus on relationship-driven solutions to customer needs across the fluoropolymer field. As vice president of business development and co-founder of ALTAFLO, Hyde has spent the last 15 years tackling specific needs and applications not being addressed by many larger firms. mary@altaflo.com.

Alexandra Peters received her Bachelor of Science degree in chemical engineering from Villanova University in 2020. She works for Arkema Inc. as an applications and standards engineer for the High Performance Polymers division. She is also a member of ASTM and ASME B31.3. alexandra.peters@arkema.com.

Marco DeAngelo received his Bachelor of Science degree in chemical engineering from Pennsylvania State University in 2020. He works for Arkema Inc. as a field sales engineer for the High Performance Polymers division. He is a member of the Material Technology Institute (MTI) and has presented on PVDF Homopolymer and Copolymer’s for corrosion control. marco.deangelo@arkema.com.